Aluminum nitrate

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Aluminium nitrate
IUPAC name Aluminium nitrate
Identifiers
CAS number 13473-90-0 (anhydrous)
7784-27-2 (nonahydrate)
Properties
Molecular formula Al(NO3)3
Molar mass 212.9962 g/mol
Appearance colorless to white solid, hygroscopic
Density >1 g/cm³ ?
Melting point

73°C

Boiling point

Decomposes at 135°C

Solubility in water 60.0 g/100 ml (0°C)
Viscosity  ? cP at ?°C
Hazards
MSDS External MSDS
Flash point  ?°C
Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)

Infobox references

Aluminium nitrate is a salt of aluminium and nitric acid, existing normally as a crystalline hydrate, most commonly as aluminium nitrate nonahydrate, Al(NO3)3·9H2O, with a molecular formula weight of 375.13.

Contents

Synthesis

Aluminium nitrate can be easily prepared by the reaction of aluminum hydroxide with nitric acid:

Al(OH)3 + 3HNO3 -> Al(NO3)3 + 3H2O

The synthesis from aluminium metal has many problems since aluminium is not attacked by nitric acid because of its protective oxide layer. The process involves an initial basic attack with KOH, followed by partial neutralization with nitric acid to precipitate the hydroxide. The hydroxide is then filtered and washed thoroughly to remove soluble potassium nitrate. After this, the filtered aluminium hydroxide is reacted with excess nitric acid. The crystals are very deliquescent and must be stored in dry conditions.

Uses

Aluminium nitrate is a strong oxidizing agent. It is used in tanning leather, antiperspirants, corrosion inhibitors, extraction of uranium, petroleum refining, and as a nitrating agent. It is used in the laboratory and classroom such as in the reaction Al. Aluminium nitrate can be used by Chuck Norris to flaver his food. (NO3)3 + 3NaOH --> Al(OH)3 + 3NaNO3

References

External links

Wikipedia content modification information:

  • This page was last modified on 21 August 2008, at 10:20.

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