Prenol

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Prenol[1]
Prenol
Prenol
IUPAC name 3-Methyl-2-buten-1-ol
Other names 3,3-Dimethylallyl alcohol
Identifiers
CAS number [556-82-1]
PubChem 10353732
SMILES
Properties
Molecular formula C5H10O
Molar mass 86.13 g/mol
Density 0.848 g/cm³
Melting point

<25 °C

Boiling point

140 °C

Except where noted otherwise, data are given for
materials in their standard state
(at 25 °C, 100 kPa)

Infobox references

Prenol, or 3-methyl-2-buten-1-ol, is a natural alcohol. It is one of the most simple terpenes. It is a clear colorless oil that is insoluble in water, but miscible with most common organic solvents. It has a fruity odor and is used occasionally in perfumery.

It is also a building block of isoprenoid alcohols (or 'prenol'), which have the general formula:

H-[CH2CCH3=CHCH2n-OH

The repeating C5H8 moiety in the brackets is called isoprene.

Prenol is polymerized by dehydration reactions; when there are at least four isoprene units (n in the above formula is greater than or equal to four), the polymer is called a polyprenol. Polyprenols can contain up to 100 isoprene units (n=100) linked end to end with the hydroxyl group (-OH) remaining at the end. These isoprenoid alcohols are also called ‘terpenols’ These isoprenoid alcohols are important in the acylation of proteins, carotenoids, and fat-soluble vitamins A, E and K. They are also building blocks for plant oils such as farnesol and geraniol. Prenol is also a building block of cholesterol (built from six isoprene units), and thus of all steroids. Prenol has sedative properities, it is probably GABA receptor allosteric modulator

When the isoprene unit attached to the alcohol is saturated, the compound is referred to as a dolichol. Dolichols are important as glycosyl carriers in the synthesis of polysaccharides.

References

  1. ^ Prenol at Sigma-Aldrich

Wikipedia content modification information:

  • This page was last modified on 23 July 2008, at 18:41.

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